The intercalation compound Li(Mn0.9Co0.1)O2 as a positive electrode for rechargeable lithium batteries

A. Robert Armstrong; Robert Gitzendanner; Alastair D. Robertson; Peter G. Bruce

doi:10.1039/A803741H

The intercalation compound Li(Mn0.9Co0.1)O2 as a positive electrode for rechargeable lithium batteries

A. Robert Armstrong, Robert Gitzendanner, Alastair D. Robertson, Peter G. Bruce^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

84 Citations (Scopus)

Abstract

By replacing only 10% of the Mn by Co in the layered lithium intercalation compound LiMnO₂ the amount of lithium that can be removed and reinserted is increased by 50% corresponding to an increase in the ability to store charge from 130 to 200 mA h g^-1 at 100 μ A cm^-2 and rendering this low cost/toxicity material of potential interest as a positive electrode in rechargeable lithium batteries; furthermore the cooperative Jahn-Teller distortion due to localised high spin Mn³⁺(3d⁴) in LiMnO₂ appears to be suppressed for Li_x(Mn_0.9Co_0.1)O₂; x < 0.9 (80% Mn³⁺ assuming Co³⁺).

Original language	English
Pages (from-to)	1833-1834
Number of pages	2
Journal	Chemical Communications
Volume	1998
Issue number	17
DOIs	https://doi.org/10.1039/A803741H
Publication status	Published - 7 Sept 1998

Keywords

intercalcation
lithium batteries
storage

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/A803741H

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title = "The intercalation compound Li(Mn0.9Co0.1)O2 as a positive electrode for rechargeable lithium batteries",

abstract = "By replacing only 10% of the Mn by Co in the layered lithium intercalation compound LiMnO2 the amount of lithium that can be removed and reinserted is increased by 50% corresponding to an increase in the ability to store charge from 130 to 200 mA h g-1 at 100 μ A cm-2 and rendering this low cost/toxicity material of potential interest as a positive electrode in rechargeable lithium batteries; furthermore the cooperative Jahn-Teller distortion due to localised high spin Mn3+(3d4) in LiMnO2 appears to be suppressed for Lix(Mn0.9Co0.1)O2; x < 0.9 (80% Mn3+ assuming Co3+).",

keywords = "intercalcation, lithium batteries, storage",

author = "Armstrong, {A. Robert} and Robert Gitzendanner and Robertson, {Alastair D.} and Bruce, {Peter G.}",

year = "1998",

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doi = "10.1039/A803741H",

language = "English",

volume = "1998",

pages = "1833--1834",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "17",

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TY - JOUR

T1 - The intercalation compound Li(Mn0.9Co0.1)O2 as a positive electrode for rechargeable lithium batteries

AU - Armstrong, A. Robert

AU - Gitzendanner, Robert

AU - Robertson, Alastair D.

AU - Bruce, Peter G.

PY - 1998/9/7

Y1 - 1998/9/7

N2 - By replacing only 10% of the Mn by Co in the layered lithium intercalation compound LiMnO2 the amount of lithium that can be removed and reinserted is increased by 50% corresponding to an increase in the ability to store charge from 130 to 200 mA h g-1 at 100 μ A cm-2 and rendering this low cost/toxicity material of potential interest as a positive electrode in rechargeable lithium batteries; furthermore the cooperative Jahn-Teller distortion due to localised high spin Mn3+(3d4) in LiMnO2 appears to be suppressed for Lix(Mn0.9Co0.1)O2; x < 0.9 (80% Mn3+ assuming Co3+).

AB - By replacing only 10% of the Mn by Co in the layered lithium intercalation compound LiMnO2 the amount of lithium that can be removed and reinserted is increased by 50% corresponding to an increase in the ability to store charge from 130 to 200 mA h g-1 at 100 μ A cm-2 and rendering this low cost/toxicity material of potential interest as a positive electrode in rechargeable lithium batteries; furthermore the cooperative Jahn-Teller distortion due to localised high spin Mn3+(3d4) in LiMnO2 appears to be suppressed for Lix(Mn0.9Co0.1)O2; x < 0.9 (80% Mn3+ assuming Co3+).

KW - intercalcation

KW - lithium batteries

KW - storage

U2 - 10.1039/A803741H

DO - 10.1039/A803741H

M3 - Article

SN - 1359-7345

VL - 1998

SP - 1833

EP - 1834

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

The intercalation compound Li(Mn0.9Co0.1)O2 as a positive electrode for rechargeable lithium batteries

Abstract

Keywords

ASJC Scopus subject areas

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