Synthesis and properties of complexes of vanadium(V) oxide trichloride with nitrogen- and oxygen-donor ligands

Charlotte D. Beard; Rosalind J. Barrie; John Evans; William Levason; Gillian Reid; Mark D. Spicer

doi:10.1002/ejic.200600513

Synthesis and properties of complexes of vanadium(V) oxide trichloride with nitrogen- and oxygen-donor ligands

Charlotte D. Beard, Rosalind J. Barrie, John Evans, William Levason^*, Gillian Reid, Mark D. Spicer

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Intensely coloured, extremely moisture sensitive complexes [VOCl ₃(L)] (L = pyridine, quinoline, Ph₃PO, Ph₃AsO, pyridine N-oxide), [VOCl₃(L)₂] (L = pyridine, Me ₃PO, pyridine N-oxide), [VOCl₃(L-L)] [L-L = 2,2′-bipyridyl, 1,10-phenanthroline, Ph₂P(O)CH ₂P(O)Ph₂, MeOCH₂CH₂OMe, 15-crown-5 or Me₂NCH₂CH₂NMe²] and [Cl ₃OV(μ-L-L)VOCl₃] [L-L =18-crown-6 or Ph ₂P(O)CH₂P(O)Ph₂] have been prepared from VOCl₃ and the appropriate ligands in dichloromethane solution. These constitute the first extended series of complexes of vanadium(V) with neutral donor ligands. They have been fully characterised by analysis, IR, UV/Visible and multinuclear (¹H, ³¹P, ⁵¹V) NMR spectroscopy, and their solution behaviour probed as a function of temperature using ⁵¹V NMR spectroscopy. Reducing ligands including phosphanes, arsanes, thio- and selenoethers immediately reduce VOCl₃ to give V^IV or V^III species. Oxygen atom transfer reactions of some of the complexes with Ph₃P, Ph₃As, Me₂Se and Bu₂S, leading to the corresponding ligand oxides are also described.

Original language	English
Pages (from-to)	4391-4398
Number of pages	8
Journal	European Journal of Inorganic Chemistry
Volume	2006
Issue number	21
Early online date	8 Sept 2006
DOIs	https://doi.org/10.1002/ejic.200600513
Publication status	Published - 23 Oct 2006
Externally published	Yes

Keywords

Coordination complexes
Multinuclear NMR spectroscopy
Vanadium

ASJC Scopus subject areas

Inorganic Chemistry

Documents and Links

10.1002/ejic.200600513

Cite this

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title = "Synthesis and properties of complexes of vanadium(V) oxide trichloride with nitrogen- and oxygen-donor ligands",

abstract = "Intensely coloured, extremely moisture sensitive complexes [VOCl 3(L)] (L = pyridine, quinoline, Ph3PO, Ph3AsO, pyridine N-oxide), [VOCl3(L)2] (L = pyridine, Me 3PO, pyridine N-oxide), [VOCl3(L-L)] [L-L = 2,2′-bipyridyl, 1,10-phenanthroline, Ph2P(O)CH 2P(O)Ph2, MeOCH2CH2OMe, 15-crown-5 or Me2NCH2CH2NMe2] and [Cl 3OV(μ-L-L)VOCl3] [L-L =18-crown-6 or Ph 2P(O)CH2P(O)Ph2] have been prepared from VOCl3 and the appropriate ligands in dichloromethane solution. These constitute the first extended series of complexes of vanadium(V) with neutral donor ligands. They have been fully characterised by analysis, IR, UV/Visible and multinuclear (1H, 31P, 51V) NMR spectroscopy, and their solution behaviour probed as a function of temperature using 51V NMR spectroscopy. Reducing ligands including phosphanes, arsanes, thio- and selenoethers immediately reduce VOCl3 to give VIV or VIII species. Oxygen atom transfer reactions of some of the complexes with Ph3P, Ph3As, Me2Se and Bu2S, leading to the corresponding ligand oxides are also described.",

keywords = "Coordination complexes, Multinuclear NMR spectroscopy, Vanadium",

author = "Beard, {Charlotte D.} and Barrie, {Rosalind J.} and John Evans and William Levason and Gillian Reid and Spicer, {Mark D.}",

year = "2006",

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doi = "10.1002/ejic.200600513",

language = "English",

volume = "2006",

pages = "4391--4398",

journal = "European Journal of Inorganic Chemistry",

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T1 - Synthesis and properties of complexes of vanadium(V) oxide trichloride with nitrogen- and oxygen-donor ligands

AU - Beard, Charlotte D.

AU - Barrie, Rosalind J.

AU - Evans, John

AU - Levason, William

AU - Reid, Gillian

AU - Spicer, Mark D.

PY - 2006/10/23

Y1 - 2006/10/23

N2 - Intensely coloured, extremely moisture sensitive complexes [VOCl 3(L)] (L = pyridine, quinoline, Ph3PO, Ph3AsO, pyridine N-oxide), [VOCl3(L)2] (L = pyridine, Me 3PO, pyridine N-oxide), [VOCl3(L-L)] [L-L = 2,2′-bipyridyl, 1,10-phenanthroline, Ph2P(O)CH 2P(O)Ph2, MeOCH2CH2OMe, 15-crown-5 or Me2NCH2CH2NMe2] and [Cl 3OV(μ-L-L)VOCl3] [L-L =18-crown-6 or Ph 2P(O)CH2P(O)Ph2] have been prepared from VOCl3 and the appropriate ligands in dichloromethane solution. These constitute the first extended series of complexes of vanadium(V) with neutral donor ligands. They have been fully characterised by analysis, IR, UV/Visible and multinuclear (1H, 31P, 51V) NMR spectroscopy, and their solution behaviour probed as a function of temperature using 51V NMR spectroscopy. Reducing ligands including phosphanes, arsanes, thio- and selenoethers immediately reduce VOCl3 to give VIV or VIII species. Oxygen atom transfer reactions of some of the complexes with Ph3P, Ph3As, Me2Se and Bu2S, leading to the corresponding ligand oxides are also described.

AB - Intensely coloured, extremely moisture sensitive complexes [VOCl 3(L)] (L = pyridine, quinoline, Ph3PO, Ph3AsO, pyridine N-oxide), [VOCl3(L)2] (L = pyridine, Me 3PO, pyridine N-oxide), [VOCl3(L-L)] [L-L = 2,2′-bipyridyl, 1,10-phenanthroline, Ph2P(O)CH 2P(O)Ph2, MeOCH2CH2OMe, 15-crown-5 or Me2NCH2CH2NMe2] and [Cl 3OV(μ-L-L)VOCl3] [L-L =18-crown-6 or Ph 2P(O)CH2P(O)Ph2] have been prepared from VOCl3 and the appropriate ligands in dichloromethane solution. These constitute the first extended series of complexes of vanadium(V) with neutral donor ligands. They have been fully characterised by analysis, IR, UV/Visible and multinuclear (1H, 31P, 51V) NMR spectroscopy, and their solution behaviour probed as a function of temperature using 51V NMR spectroscopy. Reducing ligands including phosphanes, arsanes, thio- and selenoethers immediately reduce VOCl3 to give VIV or VIII species. Oxygen atom transfer reactions of some of the complexes with Ph3P, Ph3As, Me2Se and Bu2S, leading to the corresponding ligand oxides are also described.

KW - Coordination complexes

KW - Multinuclear NMR spectroscopy

KW - Vanadium

U2 - 10.1002/ejic.200600513

DO - 10.1002/ejic.200600513

M3 - Article

AN - SCOPUS:33750994062

SN - 1434-1948

VL - 2006

SP - 4391

EP - 4398

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 21

ER -

Synthesis and properties of complexes of vanadium(V) oxide trichloride with nitrogen- and oxygen-donor ligands

Abstract

Keywords

ASJC Scopus subject areas

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