Pushing the frontiers of hard and soft scorpionate chemistry

Christopher A. Dodds; Alan R. Kennedy; John Reglinski; Mark D. Spicer

doi:10.1021/ic035167i

Pushing the frontiers of hard and soft scorpionate chemistry

Christopher A. Dodds, Alan R. Kennedy, John Reglinski^*, Mark D. Spicer

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The preparation and structure of the first scorpionate complex of a group 16 element, [Te(κ²-Tm^Me)₂], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)₂(pzH)Cl], has been synthesized and characterized.

Original language	English
Pages (from-to)	394-395
Number of pages	2
Journal	Inorganic Chemistry
Volume	43
Issue number	2
Early online date	18 Dec 2003
DOIs	https://doi.org/10.1021/ic035167i
Publication status	Published - 1 Jan 2004
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic035167i

Cite this

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title = "Pushing the frontiers of hard and soft scorpionate chemistry",

abstract = "The preparation and structure of the first scorpionate complex of a group 16 element, [Te(κ2-TmMe)2], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)2(pzH)Cl], has been synthesized and characterized.",

author = "Dodds, {Christopher A.} and Kennedy, {Alan R.} and John Reglinski and Spicer, {Mark D.}",

year = "2004",

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doi = "10.1021/ic035167i",

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journal = "Inorganic Chemistry",

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T1 - Pushing the frontiers of hard and soft scorpionate chemistry

AU - Dodds, Christopher A.

AU - Kennedy, Alan R.

AU - Reglinski, John

AU - Spicer, Mark D.

PY - 2004/1/1

Y1 - 2004/1/1

N2 - The preparation and structure of the first scorpionate complex of a group 16 element, [Te(κ2-TmMe)2], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)2(pzH)Cl], has been synthesized and characterized.

AB - The preparation and structure of the first scorpionate complex of a group 16 element, [Te(κ2-TmMe)2], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)2(pzH)Cl], has been synthesized and characterized.

U2 - 10.1021/ic035167i

DO - 10.1021/ic035167i

M3 - Article

AN - SCOPUS:1642486663

SN - 0020-1669

VL - 43

SP - 394

EP - 395

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 2

ER -

Pushing the frontiers of hard and soft scorpionate chemistry

Abstract

ASJC Scopus subject areas

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