Observations on the steric impact of N- and S-donor scorpionate ligands

Graham Steel, Rajeev Rajasekharan‐Nair, Iain A. Stepek, Alan R. Kennedy, John Reglinski*, Mark D. Spicer*

*Corresponding author for this work

Research output: Contribution to journalArticle

Abstract

A comparison is made between the steric influences of a range of zinc hydrotris(pyrazolyl)borates and zinc hydrotris-(thioimidazolyl)borates ([Zn(TpR)Cl], [Zn(TmR)Cl]; R = Me, iPr, Ph, tBu) by using inverse cone angle analysis. The study combines the crystallographic analysis of [Zn(TmiPr)Cl] and [Zn(TmPh)Cl] with the data previously deposited with the Cambridge Crystallographic Data Centre. Despite efforts to manipulate the reactive pocket around the metal centre in M(TmR) complexes, the incorporation of sterically confining substituents onto the
framework seems to have a minimal effect at the metal centre unless the group attached is very large.
Original languageEnglish
Pages (from-to)2409-2412
Number of pages4
JournalEuropean Journal of Inorganic Chemistry
Volume2016
Issue number15-16
Early online date12 Oct 2015
DOIs
Publication statusPublished - 10 Jun 2016

Keywords

  • cone angles
  • scorpionate íligands
  • steric hindrance
  • substituent íeffects
  • zinc

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