Methodologies for the analytical determination of ferrate(VI): a review

Zhiyong Luo; Meagan Strouse; JiaQian Jiang; Virender K. Sharma

doi:10.1080/10934529.2011.551723

Methodologies for the analytical determination of ferrate(VI): a review

Zhiyong Luo, Meagan Strouse, JiaQian Jiang, Virender K. Sharma

Civil Engineering and Environmental Management

Research output: Contribution to journal › Article › peer-review

123 Citations (Scopus)

Abstract

This paper reviewed different analytical techniques to determine concentrations of the environmentally-friendly oxidant ferrate(VI) (Fe^VIO^2-₄, Fe(VI)) anion in solid and solution samples. The techniques included volumetric (chromite and arsenite), electrochemical (cyclic voltammetry and potentiometry), and spectrophotometric methods (Fourier transform infrared, Mssbauer, UV-Visible, 2,2-azino-bis(3-ethylbenzothiazoline-6-sulfonate (ABTS), and fluorescence). The importance of the techniques were briefly described. This paper also presented a newly developed method for the determination of low concentrations (0.25 µM) of Fe(VI)) using the reaction between Fe(VI) and iodide (I^-), which formed the yellowish color of I^-₃ that could be measured spectrophotometrically at 351 nm.

Original language	English
Pages (from-to)	453-460
Number of pages	8
Journal	Journal of Environmental Science and Health Part A
Volume	46
Issue number	5
DOIs	https://doi.org/10.1080/10934529.2011.551723
Publication status	Published - 1 Apr 2011

Keywords

electrochemical methods
Ferrate
colorimetric technique
Mossbauer spectra

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10.1080/10934529.2011.551723

Cite this

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title = "Methodologies for the analytical determination of ferrate(VI): a review",

abstract = "This paper reviewed different analytical techniques to determine concentrations of the environmentally-friendly oxidant ferrate(VI) (FeVIO2-4, Fe(VI)) anion in solid and solution samples. The techniques included volumetric (chromite and arsenite), electrochemical (cyclic voltammetry and potentiometry), and spectrophotometric methods (Fourier transform infrared, Mssbauer, UV-Visible, 2,2-azino-bis(3-ethylbenzothiazoline-6-sulfonate (ABTS), and fluorescence). The importance of the techniques were briefly described. This paper also presented a newly developed method for the determination of low concentrations (0.25 µM) of Fe(VI)) using the reaction between Fe(VI) and iodide (I-), which formed the yellowish color of I-3 that could be measured spectrophotometrically at 351 nm.",

keywords = "electrochemical methods, Ferrate, colorimetric technique, Mossbauer spectra",

author = "Zhiyong Luo and Meagan Strouse and JiaQian Jiang and Sharma, {Virender K.}",

note = "<p>Originally published in Journal of Environmental Science and Health Part A (2011), 46 (5), pp.453–460.</p>",

year = "2011",

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doi = "10.1080/10934529.2011.551723",

language = "English",

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journal = "Journal of Environmental Science and Health Part A",

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TY - JOUR

T1 - Methodologies for the analytical determination of ferrate(VI): a review

AU - Luo, Zhiyong

AU - Strouse, Meagan

AU - Jiang, JiaQian

AU - Sharma, Virender K.

N1 - <p>Originally published in Journal of Environmental Science and Health Part A (2011), 46 (5), pp.453–460.</p>

PY - 2011/4/1

Y1 - 2011/4/1

N2 - This paper reviewed different analytical techniques to determine concentrations of the environmentally-friendly oxidant ferrate(VI) (FeVIO2-4, Fe(VI)) anion in solid and solution samples. The techniques included volumetric (chromite and arsenite), electrochemical (cyclic voltammetry and potentiometry), and spectrophotometric methods (Fourier transform infrared, Mssbauer, UV-Visible, 2,2-azino-bis(3-ethylbenzothiazoline-6-sulfonate (ABTS), and fluorescence). The importance of the techniques were briefly described. This paper also presented a newly developed method for the determination of low concentrations (0.25 µM) of Fe(VI)) using the reaction between Fe(VI) and iodide (I-), which formed the yellowish color of I-3 that could be measured spectrophotometrically at 351 nm.

AB - This paper reviewed different analytical techniques to determine concentrations of the environmentally-friendly oxidant ferrate(VI) (FeVIO2-4, Fe(VI)) anion in solid and solution samples. The techniques included volumetric (chromite and arsenite), electrochemical (cyclic voltammetry and potentiometry), and spectrophotometric methods (Fourier transform infrared, Mssbauer, UV-Visible, 2,2-azino-bis(3-ethylbenzothiazoline-6-sulfonate (ABTS), and fluorescence). The importance of the techniques were briefly described. This paper also presented a newly developed method for the determination of low concentrations (0.25 µM) of Fe(VI)) using the reaction between Fe(VI) and iodide (I-), which formed the yellowish color of I-3 that could be measured spectrophotometrically at 351 nm.

KW - electrochemical methods

KW - Ferrate

KW - colorimetric technique

KW - Mossbauer spectra

U2 - 10.1080/10934529.2011.551723

DO - 10.1080/10934529.2011.551723

M3 - Article

SN - 1532-4117

VL - 46

SP - 453

EP - 460

JO - Journal of Environmental Science and Health Part A

JF - Journal of Environmental Science and Health Part A

IS - 5

ER -

Methodologies for the analytical determination of ferrate(VI): a review

Abstract

Keywords

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