Constant current electrochemical deposition technique was used to obtain quaternary alloys of Sn-Fe-Co-Ni from a gluconate electrolyte, which to date have not been reported in the literature. For the characterization of electroplated alloys, 57Fe and 119Sn Conversion Electron Mössbauer Spectroscopy (CEMS), XRD and SEM/EDAX were used. XRD revealed the amorphous character of the novel Sn-Fe-Co-Ni electrodeposited alloys. 57Fe Mössbauer spectrum of quaternary deposit with composition of 37.0 at% Sn, 38.8 at% Fe, 16.8 at% Co and 7.4 at% Ni displayed a magnetically split sextet (B = 28.9T) with broad lines typical of iron bearing ferromagnetic amorphous alloys. Magnetically split 119Sn spectra reflecting a transferred hyperfine field (B = 2.3T) were also observed. New quaternary Sn-Fe-Co-Ni alloys were successfully prepared.
- Mössbauer Spectroscopy
Kuzmann, E., Sziráki, L., Stichleutner, S., Homonnay, Z., Lak, G. B., El-Sharif, M., & Chisholm, C. U. (2017). Mössbauer and XRD study of novel quaternary Sn-Fe-Co-Ni electroplated alloy. Hyperfine Interactions, 238, . https://doi.org/10.1007/s10751-017-1474-y