EXAFS, matrix isolation, and high temperature chemistry

I. R. Beattie; N. Binsted; W. Levason; J. S. Ogden; M. D. Spicer; N. A. Young

EXAFS, matrix isolation, and high temperature chemistry

I. R. Beattie^*, N. Binsted, W. Levason, J. S. Ogden, M. D. Spicer, N. A. Young

^*Corresponding author for this work

Research output: Contribution to journal › Conference article › peer-review

17 Citations (Scopus)

Abstract

The advantages resulting from the combination of the EXAFS (extended X-ray absorption fine structure) and matrix isolation techniques to the study of high temperature molecules are outlined. Equipement allowing the collection of EXAFS data from matrix isolated molecules at ca 9 K, combined with in situ monitoring of the isolated materials by vibrational spectroscopy is described. Metal K-edge EXAFS data of cis-[Fe(CO)₄I₂RB isolated in CH₄ and of FeCI₂ and CoCl₂ isolated in the potentially reactive matrix CO are presented and described. The FeCl₂ data show a mixture of trans- [Fe(CO)₄Cl₂] ″free″ FeCI₂ are present, whereas for Co Cl₂, only van der Waals interaction between linear CoCI₂ and the CO matrix was observed. EXAFS can also provide information about the short was order (<4th shell) in the matrix materials and this is illustrated by data for solid Kr and for Kr in Ar.

Original language	English
Pages (from-to)	71-86
Number of pages	16
Journal	High temperature science
Volume	26
Issue number	pt 1
Publication status	Published - 1988
Externally published	Yes
Event	Proceedings of the Sixth International Conference on High Temperatures - Chemistry of Inorganic Materials - Gaithersburg, United States Duration: 3 Apr 1989 → 7 Apr 1989

ASJC Scopus subject areas

General Engineering

Cite this

@article{65ad0eac80154e4ead8fca7cc6beb894,

title = "EXAFS, matrix isolation, and high temperature chemistry",

abstract = "The advantages resulting from the combination of the EXAFS (extended X-ray absorption fine structure) and matrix isolation techniques to the study of high temperature molecules are outlined. Equipement allowing the collection of EXAFS data from matrix isolated molecules at ca 9 K, combined with in situ monitoring of the isolated materials by vibrational spectroscopy is described. Metal K-edge EXAFS data of cis-[Fe(CO)4I2RB isolated in CH4 and of FeCI2 and CoCl2 isolated in the potentially reactive matrix CO are presented and described. The FeCl2 data show a mixture of trans- [Fe(CO)4Cl2] ″free″ FeCI2 are present, whereas for Co Cl2, only van der Waals interaction between linear CoCI2 and the CO matrix was observed. EXAFS can also provide information about the short was order (<4th shell) in the matrix materials and this is illustrated by data for solid Kr and for Kr in Ar.",

author = "Beattie, {I. R.} and N. Binsted and W. Levason and Ogden, {J. S.} and Spicer, {M. D.} and Young, {N. A.}",

year = "1988",

language = "English",

volume = "26",

pages = "71--86",

journal = "High temperature science",

issn = "0018-1536",

publisher = "Humana Press",

number = "pt 1",

note = "Proceedings of the Sixth International Conference on High Temperatures - Chemistry of Inorganic Materials ; Conference date: 03-04-1989 Through 07-04-1989",

}

TY - JOUR

T1 - EXAFS, matrix isolation, and high temperature chemistry

AU - Beattie, I. R.

AU - Binsted, N.

AU - Levason, W.

AU - Ogden, J. S.

AU - Spicer, M. D.

AU - Young, N. A.

PY - 1988

Y1 - 1988

N2 - The advantages resulting from the combination of the EXAFS (extended X-ray absorption fine structure) and matrix isolation techniques to the study of high temperature molecules are outlined. Equipement allowing the collection of EXAFS data from matrix isolated molecules at ca 9 K, combined with in situ monitoring of the isolated materials by vibrational spectroscopy is described. Metal K-edge EXAFS data of cis-[Fe(CO)4I2RB isolated in CH4 and of FeCI2 and CoCl2 isolated in the potentially reactive matrix CO are presented and described. The FeCl2 data show a mixture of trans- [Fe(CO)4Cl2] ″free″ FeCI2 are present, whereas for Co Cl2, only van der Waals interaction between linear CoCI2 and the CO matrix was observed. EXAFS can also provide information about the short was order (<4th shell) in the matrix materials and this is illustrated by data for solid Kr and for Kr in Ar.

AB - The advantages resulting from the combination of the EXAFS (extended X-ray absorption fine structure) and matrix isolation techniques to the study of high temperature molecules are outlined. Equipement allowing the collection of EXAFS data from matrix isolated molecules at ca 9 K, combined with in situ monitoring of the isolated materials by vibrational spectroscopy is described. Metal K-edge EXAFS data of cis-[Fe(CO)4I2RB isolated in CH4 and of FeCI2 and CoCl2 isolated in the potentially reactive matrix CO are presented and described. The FeCl2 data show a mixture of trans- [Fe(CO)4Cl2] ″free″ FeCI2 are present, whereas for Co Cl2, only van der Waals interaction between linear CoCI2 and the CO matrix was observed. EXAFS can also provide information about the short was order (<4th shell) in the matrix materials and this is illustrated by data for solid Kr and for Kr in Ar.

M3 - Conference article

AN - SCOPUS:0024179302

SN - 0018-1536

VL - 26

SP - 71

EP - 86

JO - High temperature science

JF - High temperature science

IS - pt 1

T2 - Proceedings of the Sixth International Conference on High Temperatures - Chemistry of Inorganic Materials

Y2 - 3 April 1989 through 7 April 1989

ER -

EXAFS, matrix isolation, and high temperature chemistry

Abstract

ASJC Scopus subject areas

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