Comparative performance of catalytic Fenton oxidation with zero-valent iron (Fe(0)) in comparison with ferrous sulphate for the removal of micropollutants

Anuradha Goswami, Jia-Qian Jiang

Research output: Contribution to journalArticle

5 Downloads (Pure)

Abstract

This research aims to depict the comparative performance of micropollutants’ removal by FeSO4- and zero-valent iron (Fe(0))-catalytic Fenton oxidation and to explore the possibilities of minimising the sludge production from the process. The emerging micropollutants used for the study were gabapentin, sulfamethoxazole, diuron, terbutryn and terbuthylazine. The Taguchi method, which evaluates the signal-to-noise ratio instead of the standard deviation, was used to develop robust experimental conditions. Though both FeSO4- and Fe(0)-catalytic Fenton oxidation were able to completely degrade the stated micropollutants, the Fe(0)-catalytic Fenton process delivered better removal of dissolved organic carbon (DOC; 70%) than FeSO4 catalytic Fenton oxidation (45%). Fe(0)-catalytic Fenton oxidation facilitated heterogeneous treatment functions, which eliminated toxicity from contaminated solution and there was no recognisable sludge production.
Original languageEnglish
Article number2181
Number of pages15
JournalApplied Sciences
Volume9
Issue number11
DOIs
Publication statusPublished - 28 May 2019

Fingerprint

ferrous sulfate
Catalytic oxidation
sulfates
Iron
iron
oxidation
sludge
Diuron
Taguchi methods
Sulfamethoxazole
Organic carbon
toxicity
Toxicity
standard deviation
emerging
Signal to noise ratio
signal to noise ratios
Sulfates
carbon

Keywords

  • Fenton oxidation
  • ferrous sulphate (FeSO4)
  • micropollutants (MPs)
  • sludge volume index (SVI)
  • Taguchi method
  • toxicity assessment
  • zero-valent iron (Fe(0))

Cite this

@article{55a7de49249642bcb625246e99feadbc,
title = "Comparative performance of catalytic Fenton oxidation with zero-valent iron (Fe(0)) in comparison with ferrous sulphate for the removal of micropollutants",
abstract = "This research aims to depict the comparative performance of micropollutants’ removal by FeSO4- and zero-valent iron (Fe(0))-catalytic Fenton oxidation and to explore the possibilities of minimising the sludge production from the process. The emerging micropollutants used for the study were gabapentin, sulfamethoxazole, diuron, terbutryn and terbuthylazine. The Taguchi method, which evaluates the signal-to-noise ratio instead of the standard deviation, was used to develop robust experimental conditions. Though both FeSO4- and Fe(0)-catalytic Fenton oxidation were able to completely degrade the stated micropollutants, the Fe(0)-catalytic Fenton process delivered better removal of dissolved organic carbon (DOC; 70{\%}) than FeSO4 catalytic Fenton oxidation (45{\%}). Fe(0)-catalytic Fenton oxidation facilitated heterogeneous treatment functions, which eliminated toxicity from contaminated solution and there was no recognisable sludge production.",
keywords = "Fenton oxidation, ferrous sulphate (FeSO4), micropollutants (MPs), sludge volume index (SVI), Taguchi method, toxicity assessment , zero-valent iron (Fe(0))",
author = "Anuradha Goswami and Jia-Qian Jiang",
note = "Acceptance from webpage",
year = "2019",
month = "5",
day = "28",
doi = "10.3390/app9112181",
language = "English",
volume = "9",
number = "11",

}

Comparative performance of catalytic Fenton oxidation with zero-valent iron (Fe(0)) in comparison with ferrous sulphate for the removal of micropollutants. / Goswami, Anuradha; Jiang, Jia-Qian.

In: Applied Sciences, Vol. 9, No. 11, 2181, 28.05.2019.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Comparative performance of catalytic Fenton oxidation with zero-valent iron (Fe(0)) in comparison with ferrous sulphate for the removal of micropollutants

AU - Goswami, Anuradha

AU - Jiang, Jia-Qian

N1 - Acceptance from webpage

PY - 2019/5/28

Y1 - 2019/5/28

N2 - This research aims to depict the comparative performance of micropollutants’ removal by FeSO4- and zero-valent iron (Fe(0))-catalytic Fenton oxidation and to explore the possibilities of minimising the sludge production from the process. The emerging micropollutants used for the study were gabapentin, sulfamethoxazole, diuron, terbutryn and terbuthylazine. The Taguchi method, which evaluates the signal-to-noise ratio instead of the standard deviation, was used to develop robust experimental conditions. Though both FeSO4- and Fe(0)-catalytic Fenton oxidation were able to completely degrade the stated micropollutants, the Fe(0)-catalytic Fenton process delivered better removal of dissolved organic carbon (DOC; 70%) than FeSO4 catalytic Fenton oxidation (45%). Fe(0)-catalytic Fenton oxidation facilitated heterogeneous treatment functions, which eliminated toxicity from contaminated solution and there was no recognisable sludge production.

AB - This research aims to depict the comparative performance of micropollutants’ removal by FeSO4- and zero-valent iron (Fe(0))-catalytic Fenton oxidation and to explore the possibilities of minimising the sludge production from the process. The emerging micropollutants used for the study were gabapentin, sulfamethoxazole, diuron, terbutryn and terbuthylazine. The Taguchi method, which evaluates the signal-to-noise ratio instead of the standard deviation, was used to develop robust experimental conditions. Though both FeSO4- and Fe(0)-catalytic Fenton oxidation were able to completely degrade the stated micropollutants, the Fe(0)-catalytic Fenton process delivered better removal of dissolved organic carbon (DOC; 70%) than FeSO4 catalytic Fenton oxidation (45%). Fe(0)-catalytic Fenton oxidation facilitated heterogeneous treatment functions, which eliminated toxicity from contaminated solution and there was no recognisable sludge production.

KW - Fenton oxidation

KW - ferrous sulphate (FeSO4)

KW - micropollutants (MPs)

KW - sludge volume index (SVI)

KW - Taguchi method

KW - toxicity assessment

KW - zero-valent iron (Fe(0))

U2 - 10.3390/app9112181

DO - 10.3390/app9112181

M3 - Article

VL - 9

IS - 11

M1 - 2181

ER -