In this paper we report on a very sensitive biosensor based on gold asymmetric nanoantennas that are capable of enhancing the molecular resonances of C-H bonds. The nanoantennas are arranged as arrays of asymmetric-split H-shape (ASH) structures, tuned to produce plasmonic resonances with reflectance double peaks within the mid-infrared vibrational resonances of C-H bonds for the assay of deposited films of the molecule 17ß- estradiol (E2), used as an analyte. Measurements and numerical simulations of the reflectance spectra have enabled an estimated enhancement factor on the order of 105 to be obtained for a thin film of E2 on the ASH array. A high sensitivity value of 2335 nm/RIU was achieved, together with a figure of merit of approximately 8. Our experimental results were corroborated using numerical simulations for the C-H stretch vibrational resonances from the analyte, superimposed on the plasmonic resonances of the ASH nanoantennas.
- molecular resonances
Mbomson, I. G., Tabor, S., Lahiri, B., Sharpe, G., McMeekin, S. G., De La Rue, R. M., & Johnson, N. P. (2017). Asymmetric split H-shape nanoantennas for molecular sensing. Biomedical Optics Express, 8(1), 395-406. https://doi.org/10.1364/BOE.8.000395