Abstract
The structure of 1,3-bis(2,4,6-trimethylphenyl)-imidazol-2-ylidenesilver(I) chloride, 1, has been determined to be a monomer with weak head-to-tail H···Cl interactions in the solid state. A multinuclear NMR study using a 13Ccarbene labeled derivative, 1(13C), exhibits 13C-107,109Ag coupling in solution. Further, the solid state CP/MAS NMR parameters, including the principal components of the chemical shift tensors for both the 13C and 109Ag centers, have been determined. With the aid of DFT calculations, the orientation of the chemical shift tensors have been assigned.
Original language | English |
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Pages (from-to) | 1391-1393 |
Number of pages | 3 |
Journal | Inorganic Chemistry |
Volume | 42 |
Issue number | 5 |
Early online date | 6 Feb 2003 |
DOIs | |
Publication status | Published - 1 Mar 2003 |
Externally published | Yes |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry